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Contact:

John Edwards

(203) 744-5905

Polystyrene-Butadiene Rubbers

Here are a number of slides showing the information that can be obtained from high resolution 1H process NMR spectra taken at 57.3 MHz

These samples represent finished polymer in hexane solution. The quality of the  hexane changes in the process as does the absolute solvation ratio. This means that chemometric approaches will have a difficult time performing these analyses. The advantage of the process NMR is that the olefin and aromatic regions of the spectrum are distinct and the intensity of these groups can be used to directly measure :

monomer ratios

internal/terminal olefin ratios

residual olefin content

hydrogenation level

polystyrene block percent 

 

 

 

For more information on this topic please contact:

John Edwards

Manager, Process and Analytical NMR Services

Process NMR Associates LLC,

87A Sand Pit Rd

Danbury, CT 06810, USA

Tel: (203) 744-5905